Installation

There is a paying SaaS option, in which case your Odoo instance is hosted by Odoo and available at https://ainulindale.odoo.com/ for instance.

Databases

You can export and duplicate databases directly from the web interface (Top Right Menu -> My Databases).

You can upload attachments (PDF or picture) to an Odoo vendor bill. There is an attachment icon next to the "Send message" section button.
When you create manually a vendor bill, you need to enter invoice lines. Don't forget to remove the VAT if it's not applicable.

It seems the Payroll module does not have built-in rules for countries. For instance, you must enter manually the rules that will compute your social contributions.
Rules should be either of category "Company contribution" (if the employer pays this contribution) or "Deduction" (if it's paid by the employee, out of the gross salary).
You must first create a work contract for an employee.
Clicking on the "Compute Sheet" button will create automatically the salary computations (such as social compensations, etc).
To create the entries in the accounting journals, you should click on the "Create Draft Entry" button on the Payslip.

1024 is the bank account.
2270 holds the debt of the company to the social insurance institutions.
2800 is for the share capital.
2850 (Private share account) is used to hold debts of the company to the shareholder.
5700, 5710, 5720, 5730, 5740 are used for various social benefits (health insurance, unemployment insurance, maternity insurance etc).
6000 for rental expenses.
6700 (and subaccounts like 6710 for fiduciary) for general operating expenses.
6900 for financial expenses like bank fees.